January 28, 2025 | Julian Karas

Co-Stars Who Had Insane Chemistry


The Perfect Formula

Great chemistry between co-stars is one of the most elusive goals of filmmaking. It can elevate an average film to greatness and make a lasting impression on audiences. Let’s look at the most exceptional cases of co-stars who had insane on-screen chemistry. Some of the examples may surprise you; others will make you nod with fond recognition.

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Julia Roberts & Richard Gere

Pretty Woman (1990)

This was the breakthrough film for Roberts opposite the classic male lead Richard Gere. The simmering chemistry between these two made viewers forget the film’s improbable premise, allowing Pretty Woman to become one of the highest-grossing movies of all time.

Screenshot of the movie Pretty WomanTouchstone, Pretty Woman (1991)

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Will Smith & Eva Mendes

Hitch (2005)

This romantic comedy featured a ruthless dating coach (Smith) who has to throw his playbook out the window while pursuing the irresistible Mendes. Mendes’ beauty and intelligence, combined with Smith’s good-natured charm helped make Hitch the 10th-highest grossing film of 2005.

Screenshot of the movie HitchColumbia, Hitch (2005)

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Emma Stone & Ryan Gosling

Crazy, Stupid Love (2011)

Stone and Gosling were the perfect match in this romantic comedy that provided some crazy plot twists! Their on-screen magnetism was so successful it led to two more films co-starring the pair: Gangster Squad (2013); and La La Land (2016).

Screenshot of the movie Crazy, Stupid, Love.Carousel Productions, Crazy, Stupid, Love. (2011)

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James McAvoy & Keira Knightley

Atonement (2007)

The intense chemistry between McAvoy and Knightley fuelled this complex story set in the early days of WWII. Aided by outstanding cinematography and a haunting ending, both co-stars were nominated for BAFTAs (British Academy Film Awards).

Screenshot of the movie AtonementUniversal, Atonement (2007)

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Sandra Bullock & Bill Pullman

While You Were Sleeping (1995)

The always-appealing Bullock seems to have great chemistry with whoever she co-stars with—this time out, she was matched perfectly with the laid-back Bill Pullman. Bullock was nominated for a Golden Globe for her performance.

Screenshot of the movie While You Were SleepingHollywood Pictures, While You Were Sleeping (1995)

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Kristin Scott Thomas & Ralph Fiennes

The English Patient (1996)

The intensity of the passion between Fiennes and Scott Thomas amid swirling desert sands is one of several powerful elements driving this sweeping WWII-era tale. Fiennes and Scott Thomas both received Academy Award nominations for their efforts.

Screenshot of the movie The English PatientMiramax, The English Patient (1996)

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Harrison Ford & Carrie Fisher

The Star Wars films

The galactic adventurer never at a loss for words (Ford), and the princess as brave as she is beautiful (Fisher) were the perfect combination for the epic sci-fi series. The growing attraction between the two characters provided some nice breaks from the Star Wars films’ relentless action and special effects.

Screenshot of the movie Star Wars: Episode IV - A New HopeLucasfilm, Star Wars: Episode IV - A New Hope (1977)

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Caitriona Balfe & Sam Heughan

The Outlander series

Knowing that fans of Diana Gabaldon’s Outlander novels would demand sizzling chemistry between the TV series’ leads, all eyes were on the initial casting screen tests. Balfe and Heughan’s test lit it up, and they are still going strong in the series which anticipates its eighth and last season.

Screenshot of the TV Series OutlanderLeft Bank Pictures, Outlander (2014-)

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Teo Yoo & Greta Lee

Past Lives (2023)

Yoo and Lee are mesmerizing as two old friends longing for a time that’s passed them by in the acclaimed debut of director Celine Song. More complex and contemplative than a mere romantic comedy, the film made outstanding use of the two co-stars’ emotional range and depth.

Screenshot of the movie Past LivesA24, Past Lives (2023)

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Drew Barrymore & Adam Sandler

The Wedding Singer (1998)

These two were already friends off the set, triggering Barrymore to request the female lead opposite Sandler for this 80s throwback comedy. The combination hit it off in what turned out to be the first of three collaborations including 50 First Dates (2004) and Blended (2014).

Screenshot of the movie The Wedding SingerNew Line Cinema, The Wedding Singer (1998)

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Daniel Kaluuya & Jodie Turner-Smith

Queen & Slim (2019)

This fast-paced film about racial discrimination in policing was held together by the magnetism of the two co-stars. Kaluuya and Turner-Smith are utterly convincing in their roles as lovers and fugitives on the run.

Screenshot of the movie Queen & SlimHillman Grad, Queen & Slim (2019)

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Cate Blanchett & Rooney Mara

Carol (2015)

Blanchett and Mara excelled in this film about a woman with a failing marriage who seduces an aspiring young female photographer. Adapted from a Patricia Highsmith novel, the film (and its co-stars) effectively portrayed the forbidden nature of a lesbian romance in the early 50s.

Screenshot of the movie CarolThe Weinstein Company, Carol (2015)

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Anjelica Huston & Raul Julia

The Addams Family (1991)

This oddball film was a surprise hit, due in no small part to the on-screen chemistry between Julia and Huston. The pair performed a sensual tango in one of the flamboyant film’s high points. They would collaborate again on the sequel Addams Family Values (1993).

Screenshot of the movie The Addams FamilyParamount, The Addams Family (1991)

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Michael B Jordan & Tessa Thompson

The Creed film series

Thompson and Jordan’s on-screen relationship was a hit with fans—the two actors actually went to marriage counselling together to improve their on-screen chemistry. It definitely helped. Their moving scenes got the Creed series up and running, and they haven’t looked back since; Creed 4 is now in development.

Screenshot of the movie Creed IIIMGM, Creed III (2023)

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Nicole Kidman & Ewan McGregor

Moulin Rouge! (2001)

The memorable chemistry between Kidman and McGregor was somewhat lost in the critical acclaim for the film as a whole. Both actors credit the production’s long, demanding vocal and dance training for bringing them closer together as co-stars.

Screenshot of the movie Moulin Rouge!Twentieth Century, Moulin Rouge! (2001)

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Michael Douglas & Kathleen Turner

Romancing the Stone (1984)

These two co-stars meshed perfectly with each other— and with the over-the-top adventure story that was Romancing the Stone. The Turner-Douglas formula was so successful that the pair made two additional films together: The Jewel of the Nile (1986); and The War of the Roses (1989).

Screenshot of the movie Romancing the StoneTwentieth Century, Romancing the Stone (1984)

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Liv Tyler & Viggo Mortensen

The Lord of the Rings trilogy

Though a background thread to the fantasy high adventure story, the relationship of Mortensen’s Aragorn and Tyler’s elf princess Arwen added a welcome romantic and mythical dimension to the Rings series.

Screenshot of the movie The Lord of the Rings: The Fellowship of the RingNew Line Cinema, The Lord of the Rings: The Fellowship of the Ring (2001)

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Noémie Merlant & Adèle Haenel

Portrait of a Lady On Fire (2019)

The intensity of the passion between these two co-stars was aided by outstanding cinematography and a strong script. The 1700s period piece won praise from critics as a groundbreaking LGBT film and for its high quality in general.

Screenshot of the movie Portrait of a Lady on FireArte France Cinéma, Portrait of a Lady on Fire (2019)

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Humphrey Bogart & Ingrid Bergman

Casablanca (1942)

The chemistry of these co-stars has become a Hollywood legend. The cynical Rick Blaine (Bogart) and the mysterious Ilsa (Bergman) are one of the classic cinematic pairings of all time. Watch this WWII era classic and find out why.

Screenshot of the movie CasablancaWarner Bros., Casablanca (1942)

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Robin Williams & Nathan Lane

The Birdcage (1996)

Williams and Lane’s portrayal of a gay couple trying to hide their relationship from their son’s wealthy conservative in-laws was praised for its humorous sequences. Critics now regard it as a turning point in the history of LGBT film for its lighthearted portrayal of gay relationships.

Screenshot of the movie The BirdcageUnited Artists, The Birdcage (1966)

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Kate Winslet & Leonardo DiCaprio

Titanic (1997)

The technical achievements of James Cameron’s mega-budget shipwreck epic were made more timeless and dramatic by the seafaring love story between DiCaprio and Winslet.

Screenshot from the film Titanic (1997)Paramount, Titanic (1997)

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Rachel Weisz & Rachel McAdams

Disobedience (2017)

The two Rachels (Weisz and McAdams) won acclaim for their acting depth and personal chemistry in this film that explores the rekindling of a forbidden romance under the disapproving eyes of a strict orthodox religious community.

Screenshot of the movie DisobedienceFilm4, Disobedience (2017)

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Chris Pine & Anne Hathaway

The Princess Diaries 2: Royal Engagement (2004)

In a breakthrough for Hathaway and the first major role for Chris Pine, the pair’s insane chemistry helped make this Disney film a box-office success. The co-stars and their storybook romance still have fans clamoring for a sequel two decades later.

Screenshot of the movie The Princess Diaries 2: Royal EngagementWalt Disney, The Princess Diaries 2: Royal Engagement (2004)

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Scarlett Johansson & Chris Evans

The Perfect Score (2004)

Johansson and Evans established the chemistry that would serve them through eight additional films together. This movie about desperate students stealing the answers to a big final exam was more popular with young audiences than it was with critics, but it offers an interesting look at the co-stars’ pre-Avengers work.

Screenshot of the movie The Perfect ScoreParamount, The Perfect Score (2004)

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Tom Holland & Zendaya

Spider-Man: Homecoming (2017)

Zendaya wasn’t on-screen for much of Spider-Man: Homecoming, but she still made a big impression, especially on co-star Tom Holland. The two actors have been a couple ever since.

Screenshot of the movie Spider-Man: HomecomingMarvel, Spider-Man: Homecoming (2017)

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Saoirse Ronan & Timothee Chalemet

Lady Bird (2017)

The affection between Saoirse (pronounced shur-seh) Ronan and Timothee Chalemet was obvious as the two played high-school seniors going separate ways in this intriguing coming-of-age story. The pair have worked together on two other films since then: Little Women (2019); and The French Dispatch (2021).

Screenshot of the movie Lady BirdEntertainment 360, Lady Bird (2017)

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Javier Bardem & Penelope Cruz

Everybody Knows (2018)

Cruz and Bardem were married for eight years by the time they worked together in this complex Spanish-language drama. The couple won praise for the intense chemistry they brought to the screen; both actors were nominated for Goya (Spanish Film Academy) Awards.

Screenshot of the movie Everybody KnowsMemento Films Production, Everybody Knows (2018)

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Sanaa Lathan & Omar Epps

Love & Basketball (2000)

Lathan and Epps provided great emotional depth to this moving portrait of young athletes desperately trying to break into the big leagues. The work of the two protagonists has gained Love & Basketball a dedicated fan following over the years.

Screenshot of the movie Love & Basketball40 Acres & A Mule Filmworks, Love & Basketball (2000)

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Bradley Cooper & Jennifer Lawrence

Silver Linings Playbook (2012)

Director David O Russell thought at first that Jennifer Lawrence was too young to play her part, but Lawrence made the character of Tiffany Maxwell her own. Her infectious chemistry with co-star Bradley Cooper made Silver Linings Playbook a major box-office and critical success.

Screenshot of the movie Silver Linings PlaybookThe Weinstein Company, Silver Linings Playbook (2012)

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Kate Hudson & Matthew McConaughey

How To Lose A Guy In 10 Days (2003)

It was obvious that Hudson and McConaughey had a blast during the filming of this romantic comedy. In spite of the film’s formulaic silliness, even the most stone-faced critics grudgingly praised Hudson and McConaughey’s screwball antics. Hey, you can’t be serious all the time!

Screenshot of the movie How to Lose a Guy in 10 Days

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Eugene Levy & Catherine O’Hara

Schitt’s Creek TV series

Writing another—and possibly greatest—chapter in their parallel careers as SCTV comedians, Levy and O’Hara played off each other perfectly as a pair of lovably pretentious nitwits living in a small-town motel.

Screenshot of the TV Series Schitt's CreekCBS, Schitt's Creek (2015–2020)

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Angela Bassett & Denzel Washington

Malcolm X (1992)

The chemistry of these co-stars was a slow burn in the Spike Lee biopic about the influential Black Muslim leader. Bassett’s role as the wife of Washington’s Malcolm added a fascinating personal dimension to the film’s historical significance.

Screenshot of the movie Malcolm X40 Acres & A Mule Filmworks, Malcolm X (1992)

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Jake Gyllenhaal & Heath Ledger

Brokeback Mountain (2005)

Not only did Gyllenhaal and Ledger have intense chemistry in this groundbreaking film, but they also shared a commitment to the message and spirit of Brokeback Mountain as well. The sincerity and nuance of their performances made the film a massive—and lasting—success with audiences and critics alike.

Screenshot of the movie Brokeback MountainFocus Features, Brokeback Mountain (2005)

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Keanu Reeves & Carrie-Anne Moss

The Matrix films

The Matrix was such a mind-bending and original story that it was easy to overlook the outstanding chemistry between Reeves and Moss. Depicting a love story that carried through the sequels, the intrepid pair are still a big-screen gem.

Screenshot of the movie The MatrixWarner Bros., The Matrix (1999)

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Jennifer Lopez & George Clooney

Out Of Sight (1998)

Clooney and Lopez had a romantic chemistry in this film that is still praised by critics and filmmakers nearly 30 years later. The electricity between the two co-stars was woven effectively into a comedic hard-boiled crime plot that earned Out Of Sight a 94% rating on Rotten Tomatoes.

Screenshot of the movie Out of SightUniversal, Out of Sight (1998)

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Billy Crystal & Meg Ryan

When Harry Met Sally (1989)

Ryan and Crystal were both at their best in this iconic film. When Harry Met Sally became one of the most memorable romantic comedies of all time for its humor, perceptive observations on relationships, and insane chemistry between the two co-stars.

Screenshot of the movie When Harry Met Sally...Castle Rock, When Harry Met Sally... (1989)

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Taraji P Henson & Terrence Howard

Hustle & Flow (2005)

Henson and Howard smoldered in the first of their many collaborations. Hustle & Flow offers fans of the Empire series a look back at the pair’s first project together in one of the great all-time hip-hop films.

Screenshot of the movie Hustle & FlowHomegrown Pictures, Hustle & Flow (2005)

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Jared Gilman & Kara Hayward

Moonrise Kingdom (2012)

The youngest pairing on this list, Hayward and Gilman’s depiction of childhood romance was the centerpiece of director Wes Anderson’s fantasy coming-of-age story Moonrise Kingdom. The debut film for both Hayward and Gilman, the two have since established solid acting careers.

Screenshot of the movie Moonrise KingdomIndian Paintbrush, Moonrise Kingdom (2012)

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Patrick Swayze & Jennifer Grey

Dirty Dancing (1987)

They were having the time of their lives on-screen, but these two co-stars had a difficult relationship on set. The actors had years of bad blood between them, which made filming a nightmare. Luckily for us, Director Emile Ardolino and choreographer Kenny Ortega managed to channel the tension between Swayze and Grey into an enduring romantic classic.

Screenshot of the movie Dirty DancingVestron Pictures, Dirty Dancing (1987)


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